신소재공학과

Seminar

Extra Form
Date 20180313

MSE Regular Seminar



■ Title Dimensional Organic Networks for Energy Conversion and Storage


■ Speaker : Prof. Jong-Beom Baek (School of Energy and Chemical Engineering, UNIST)

  

■ Date and Time : 13th of March, 2018 (Tue) 16:00

 

■ Venue : Applied Engineering Department (W1-1) Multimedia Lecture Hall (1st Floor)

 

 Host :  Prof. Sang Ouk Kim

  

 Abstract :  

Since the discovery of graphene in 2004,1 conjugated two-dimensional (2D) organic networks have attracted immense interest due to their unusual electronic, optoelectronic, magnetic and electrocatalytic properties. In addition, their tunable structures and properties promise to offer more opportunities than graphene in various applications. However, even after years of intensive exploration of 2D materials in science and technology, facile and scalable methods capable of producing stable 2D networks with uniformly decorated heteroatoms with/without holes remain limited. To overcome these issues, new layered 2D organic networks have been designed and synthesized. They have uniformly distributed heteroatoms,2 holes with heteroatoms3 and transition metal nanoparticles in the holes.4 The structures were confirmed by scanning tunneling microscopy (STM). Based on the stoichiometry of the basal plane, they were, respectively, designated C3N, C2N and M@C2N (M = Co, Ni, Pd, Pt, Ru). Their electronic and electrical properties were evaluated by electrooptical and electrochemical measurements along with density-functional theory (DFT) calculations. Furthermore, robust three-dimensional (3D) cage-like organic networks have also been constructed and they show high sorption properties.5,6 The results suggest that these newly-developed 2D and 3D organic networks offer greater opportunities, from wet-chemistry to device applications.  

 

References:

[1] Novoselov, et al. Electric field effect in atomically thin carbon film. Science 2004, 306, 666.

[2] Mahmood, et al. Two-dimensional polyaniline (C3N) from carbonized organic single crystals. Proceedings of National Academy of Sciences, USA 2016, 113, 7414.

[3] Mahmood, et al. Nitrogenated holey two-dimensional structure. Nature Communications 2015, 6, 6486.

[4] Mahmood, et al. An efficient and pH-universal ruthenium-based catalyst for the hydrogen evolution reaction. Nature Nanotechnology 2017, 12, 441.

[5] Bae, et al. Forming a three dimensional porous organic network via explosion of organic single crystals in solid-stateNature Communications 2017, 8, 159-Highlighted in Nature Nanotechnology 2018, 13, 4.9.

[6] Mahmood, et al. A robust 3D cage-like ultramicroporous network structure with high gas uptahe capacities. Angewandte Chemie International Edition 2018, DOI: 10.1002/ange.201800218.


List of Articles
No. Category Subject Author Date Views
Notice Regular 12/4 (Tue) Prof. Doo Seok Jeong (Hanyang Univ., Department of MSE) ADMINI 2018.11.30 110
Notice Regular 11/27 (Tue) Prof. Seong-Jun Jeong (Soongsil Univ.) ADMINI 2018.11.26 110
Notice Regular 11/20 (Tue) Prof. Youn Soo Kim (Department of MSE, POSTECH) ADMINI 2018.11.19 167
Notice Special 11/14 (Wed) Prof. Hui-Ming Cheng (Director and Professor, Tsinghua University, IMR CAS) ADMINI 2018.11.13 144
Notice Special 11/20 (Tue) Prof. Alfonso H. W. Ngan (Department of Mechanical Engineering, University of Hong Kong) file ADMINI 2018.11.13 157
Notice Regular 11/13 (Tue) Dr. Kang-Wook Lee (SK Hynix) ADMINI 2018.11.13 105
Notice Regular 11/6 (Tue) Prof. Dongchan Jang (KAIST NQE) ADMINI 2018.11.02 179
Notice Special 11/2 (Fri) Dr. Sungbong Park (Intel Corporation) ADMINI 2018.10.30 207
264 Regular 6/5 (Tue) Prof. Sunghwan Lee (Baylor University) ADMINI 2018.06.05 603
263 Regular 5/29 (Tue) Prof. Sang Ho Oh (Yonsei Univ. College of Medicine) ADMINI 2018.05.29 583
262 Regular 5/15 (Tue) Prof. Myung Gil Kim (Dept. of Chemistry, Chung-Ang Univ.) ADMINI 2018.05.15 797
261 Regular 5/8 (Tue) Prof. Ju-Young Kim (UNIST MSE) ADMINI 2018.05.09 710
260 Regular 5/1 (Tue) Prof. Duk-Yong Yoon (KAIST MSE) ADMINI 2018.04.30 1172
259 Regular 4/24 (Tue) Kyeong Ho Chang (CEO, Innox Advanced Materials) ADMINI 2018.04.23 735
258 Regular 4/10 (Tue) Prof. Ki Jun, Yu (Yonsei Univ., School of Electrical and Electronic Engineering) ADMINI 2018.04.09 812
257 Regular 4/3 (Tue) Master Byung-Gi Choi (Samsung Advanced Institute of Technology) ADMINI 2018.04.02 693
256 Regular 3/27 (Tue) Prof. Seungbum Hong (KAIST MSE) ADMINI 2018.03.26 644
255 Regular 3/20 (Tue) Prof. Jung In-Ho (Seoul National University, MSE) ADMINI 2018.03.20 545
» Regular 3/13 (Tue) Prof. Jong-Beom Baek (School of Energy and Chemical Engineering, UNIST) ADMINI 2018.03.13 511
253 Regular 3/6 (Tue) Prof. Seok-Young Ryu (KAIST CS) ADMINI 2018.03.05 431
252 Regular 2/27 (Tue) Dr. Jin-Woo Han (NASA) ADMINI 2018.02.27 495
251 Special 2/20 (Tue) Dr. Jae Beom Jang (Sungkyunkwan Univ) ADMINI 2018.02.19 456
250 Special 2/8 (Thu) Prof. Pei-Chen Su (Nanyang Technological University) file ADMINI 2018.02.05 465
249 Special 2/13 (Tue) Prof. Sungkyu Kim (Northwestern Univ) ADMINI 2018.01.31 523
248 Special 1/9 (Tue) Dr. Choon Won Byeon, ETRI ADMINI 2018.01.09 526
247 12/23 (Sat) Prof. Liangbing (Bing) Hu/Univ. of Maryland file ADMINI 2017.12.22 542
246 Regular 11/28 (Tue) Dr. Woo-Jin Lee (Ministry of Science and ICT.) ADMINI 2017.11.24 1186
245 Special 11/24 (Fri) Takashi NOGUCH (University of the Ryukyus) ADMINI 2017.11.23 852
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